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Ammonia | CAS 7664-41-7 | ||
NH3 | RTECS BO0875000 | ||
Synonyms & Trade Names Anhydrous ammonia, Aqua ammonia, Aqueous ammonia [Note: Often used in an aqueous solution.] |
DOT ID & Guide 1005 125 (anhydrous) 2672 154 (10-35% solution) 2073 125 (>35-50% solution) 1005 125 (>50% solution) |
Exposure Limits |
NIOSH REL: TWA 25 ppm (18 mg/m3) ST 35 ppm (27 mg/m3) | ||
OSHA PEL�: TWA 50 ppm (35 mg/m3) | |||
IDLH 300 ppm | Conversion 1 ppm = 0.70 mg/m3 |
Physical Description Colorless gas with a pungent, suffocating odor. [Note: Shipped as a liquefied compressed gas. Easily liquefied under pressure.] |
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MW: 17.0 |
BP: -28°F |
FRZ: -108°F |
Sol: 34% |
VP: 8.5 atm |
IP: 10.18 eV |
RGasD: 0.60 |
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Fl.P: NA (Gas) |
UEL: 28% |
LEL: 15% |
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[Note: Although NH3 does not meet the DOT definition of a Flammable Gas (for labeling purposes), it should be treated as one.] | |||
Incompatibilities & Reactivities Strong oxidizers, acids, halogens, salts of silver & zinc [Note: Corrosive to copper & galvanized surfaces.] |
Measurement Methods NIOSH 6015, 6016; OSHA ID188 |
Personal Protection & Sanitation Skin: Prevent skin contact Eyes: Prevent eye contact Wash skin: When contaminated (solution) Remove: When wet or contaminated (solution) Change: No recommendation Provide: Eyewash (>10%), Quick drench (>10%) |
First Aid (See procedures) Eye: Irrigate immediately (solution/liquid) Skin: Water flush immediately (solution/liquid) Breathing: Respiratory support Swallow: Medical attention immediately (solution) |
Respirator Recommendations
NIOSH Up to 250 ppm: (APF = 10) Any chemical cartridge respirator with cartridge(s) providing protection against the compound of concern*/(APF = 10) Any supplied-air respirator* Up to 300 ppm: (APF = 25) Any supplied-air respirator operated in a continuous-flow mode*/(APF = 25) Any powered, air-purifying respirator with cartridge(s) providing protection against the compound of concern*/(APF = 50) Any chemical cartridge respirator with a full facepiece and cartridge(s) providing protection against the compound of concern/(APF = 50) Any air-purifying, full-facepiece respirator (gas mask) with a chin-style, front- or back-mounted canister providing protection against the compound of concern/(APF = 50) Any self-contained breathing apparatus with a full facepiece/(APF = 50) Any supplied-air respirator with a full facepiece Emergency or planned entry into unknown concentrations or IDLH conditions: (APF = 10,000) Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode/(APF = 10,000) Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained positive-pressure breathing apparatus Escape: (APF = 50) Any air-purifying, full-facepiece respirator (gas mask) with a chin-style, front- or back-mounted canister providing protection against the compound of concern/Any appropriate escape-type, self-contained breathing apparatus |
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Exposure Routes inhalation, ingestion (solution), skin and/or eye contact (solution/liquid) | |
Symptoms Irritation eyes, nose, throat; dyspnea (breathing difficulty), wheezing, chest pain; pulmonary edema; pink frothy sputum; skin burns, vesiculation; liquid: frostbite | |
Target Organs
Eyes, skin, respiratory system |
See also: INTRODUCTION |