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Azinphos-methyl | CAS 86-50-0 | ||
C10H12O3PS2N3 | RTECS TE1925000 | ||
Synonyms & Trade Names O,O-Dimethyl-S-4-oxo-1,2,3-benzotriazin-3(4H)-ylmethyl phosphorodithioate; Guthion®; Methyl azinphos |
DOT ID & Guide 2783 152 |
Exposure Limits |
NIOSH REL: TWA 0.2 mg/m3 [skin] | ||
OSHA PEL: TWA 0.2 mg/m3 [skin] | |||
IDLH 10 mg/m3 | Conversion |
Physical Description Colorless crystals or a brown, waxy solid. [insecticide] |
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MW: 317.3 |
BP: Decomposes |
MLT: 163°F |
Sol: 0.003% |
VP: 8 x 10-9 mmHg |
IP: ? |
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Sp.Gr: 1.44 |
Fl.P: NA |
UEL: NA |
LEL: NA |
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Noncombustible Solid | |||
Incompatibilities & Reactivities Strong oxidizers, acids |
Measurement Methods NIOSH 5600 |
Personal Protection & Sanitation Skin: Prevent skin contact Eyes: Prevent eye contact Wash skin: When contaminated Remove: When wet or contaminated Change: Daily Provide: Quick drench |
First Aid (See procedures) Eye: Irrigate immediately Skin: Soap wash immediately Breathing: Respiratory support Swallow: Medical attention immediately |
Respirator Recommendations
NIOSH/OSHA Up to 2 mg/m3: (APF = 10) Any chemical cartridge respirator with organic vapor cartridge(s) in combination with a dust, mist, and fume filter/(APF = 10) Any supplied-air respirator Up to 5 mg/m3: (APF = 25) Any supplied-air respirator operated in a continuous-flow mode/(APF = 25) Any powered, air-purifying respirator with organic vapor cartridge(s) in combination with a dust, mist, and fume filter Up to 10 mg/m3: (APF = 50) Any chemical cartridge respirator with a full facepiece and organic vapor cartridge(s) in combination with a high-efficiency particulate filter/(APF = 50) Any air-purifying, full-facepiece respirator (gas mask) with a chin-style, front- or back-mounted organic vapor canister having a high-efficiency particulate filter/(APF = 50) Any powered, air-purifying respirator with a tight-fitting facepiece and organic vapor cartridge(s) in combination with a high-efficiency particulate filter/(APF = 50) Any supplied-air respirator that has a tight-fitting facepiece and is operated in a continuous-flow mode/(APF = 50) Any self-contained breathing apparatus with a full facepiece/(APF = 50) Any supplied-air respirator with a full facepiece Emergency or planned entry into unknown concentrations or IDLH conditions: (APF = 10,000) Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode/(APF = 10,000) Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained positive-pressure breathing apparatus Escape: (APF = 50) Any air-purifying, full-facepiece respirator (gas mask) with a chin-style, front- or back-mounted organic vapor canister having a high-efficiency particulate filter/Any appropriate escape-type, self-contained breathing apparatus |
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Exposure Routes inhalation, skin absorption, ingestion, skin and/or eye contact | |
Symptoms Miosis; ache eyes; blurred vision, lacrimation (discharge of tears), rhinorrhea (discharge of thin mucus); headache; tightness chest, wheezing, laryngeal spasm; salivation; cyanosis; anorexia; nausea, vomiting, diarrhea; sweating; twitching, paralysis, convulsions; low blood pressure, cardiac irregularities | |
Target Organs
respiratory system, central nervous system, cardiovascular system, blood cholinesterase |
See also: INTRODUCTION |