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3,3'-Dichlorobenzidine (and its salts) | CAS 91-94-1 | ||
NH2ClC6H3C6H3ClNH2 | RTECS DD0525000 | ||
Synonyms & Trade Names 4,4'-Diamino-3,3'-dichlorobiphenyl; Dichlorobenzidine base; o,o'-Dichlorobenzidine; 3,3'-Dichlorobiphenyl-4,4'-diamine; 3,3'-Dichloro-4,4'-biphenyldiamine; 3,3'-Dichloro-4,4'-diaminobiphenyl |
DOT ID & Guide |
Exposure Limits |
NIOSH REL: Ca See Appendix A | ||
OSHA PEL: [1910.1007] See Appendix B | |||
IDLH Ca [N.D.] | Conversion |
Physical Description Gray to purple, crystalline solid. |
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MW: 253.1 |
BP: 788°F |
MLT: 271°F |
Sol(59°F): 0.07% |
VP: ? |
IP: ? |
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Sp.Gr: ? |
Fl.P: ? |
UEL: ? |
LEL: ? |
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Incompatibilities & Reactivities None reported |
Measurement Methods NIOSH 5509; OSHA 65 |
Personal Protection & Sanitation Skin: Prevent skin contact Eyes: Prevent eye contact Wash skin: When contaminated/Daily Remove: When wet or contaminated Change: Daily Provide: Eyewash, Quick drench |
First Aid (See procedures) Eye: Irrigate immediately Skin: Soap wash immediately Breathing: Respiratory support Swallow: Medical attention immediately |
Respirator Recommendations
NIOSH At concentrations above the NIOSH REL, or where there is no REL, at any detectable concentration: (APF = 10,000) Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode/(APF = 10,000) Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained positive-pressure breathing apparatus Escape: (APF = 50) Any air-purifying, full-facepiece respirator with a high-efficiency particulate filter/Any appropriate escape-type, self-contained breathing apparatus |
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Exposure Routes inhalation, skin absorption, ingestion, skin and/or eye contact | |
Symptoms Skin sensitization, dermatitis; headache, dizziness; caustic burns; frequent urination, dysuria; hematuria (blood in the urine); gastrointestinal upset; upper respiratory infection; [potential occupational carcinogen] | |
Target Organs
Bladder, liver, lung, skin, gastrointestinal tract Cancer Site [in animals: liver & bladder cancer] |
See also: INTRODUCTION |