NIOSH Pocket Guide to Chemical Hazards

Hydroquinone CAS 123-31-9
C6H4(OH)2 RTECS MX3500000
Synonyms & Trade Names
p-Benzenediol; 1,4-Benzenediol; Dihydroxybenzene; 1,4-Dihydroxybenzene; Quinol
DOT ID & Guide
2662 153
Exposure
Limits
NIOSH REL: C 2 mg/m3 [15-minute]
OSHA PEL: TWA 2 mg/m3
IDLH 50 mg/m3 Conversion
Physical Description
Light-tan, light-gray, or colorless crystals.
MW: 110.1
BP: 545°F
MLT: 338°F
Sol: 7%
VP: 0.00001 mmHg
IP: 7.95 eV

Sp.Gr: 1.33
Fl.P: 329°F (Molten)
UEL: ?
LEL: ?

Combustible Solid; dust cloud may explode if ignited in an enclosed area.
Incompatibilities & Reactivities
Strong oxidizers, alkalis
Measurement Methods
NIOSH 5004
Personal Protection & Sanitation
Skin: Prevent skin contact
Eyes: Prevent eye contact
Wash skin: When contaminated
Remove: When wet or contaminated
Change: Daily
Provide: Eyewash (>7%)
First Aid (See procedures)
Eye: Irrigate immediately
Skin: Water flush
Breathing: Respiratory support
Swallow: Medical attention immediately
Respirator Recommendations NIOSH/OSHA
Up to 50 mg/m3: (APF = 25) Any powered, air-purifying respirator with a dust filter/(APF = 50) Any air-purifying, full-facepiece respirator with a high-efficiency particulate filter/(APF = 50) Any supplied-air respirator that has a tight-fitting facepiece and is operated in a continuous-flow mode/(APF = 50) Any self-contained breathing apparatus with a full facepiece/(APF = 50) Any supplied-air respirator with a full facepiece
Emergency or planned entry into unknown concentrations or IDLH conditions: (APF = 10,000) Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode/(APF = 10,000) Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained positive-pressure breathing apparatus
Escape: (APF = 50) Any air-purifying, full-facepiece respirator with a high-efficiency particulate filter/Any appropriate escape-type, self-contained breathing apparatus
Exposure Routes inhalation, ingestion, skin and/or eye contact
Symptoms Irritation eyes: conjunctivitis; keratitis (inflammation of the cornea); central nervous system excitement; colored urine, nausea, dizziness, suffocation, rapid breathing; muscle twitching, delirium; collapse; skin irritation, sensitization, dermatitis
Target Organs Eyes, skin, respiratory system, central nervous system
See also: INTRODUCTION