NIOSH Pocket Guide to Chemical Hazards

Rhodium (metal fume and insoluble compounds, as Rh) CAS 7440-16-6 (metal)
Rh (metal) RTECS VI9069000 (metal)
Synonyms & Trade Names
Rhodium metal: Elemental rhodium
Synonyms of other insoluble rhodium compounds vary depending upon the specific compound.
DOT ID & Guide
Exposure
Limits
NIOSH REL: TWA 0.1 mg/m3
OSHA PEL: TWA 0.1 mg/m3
IDLH 100 mg/m3 (as Rh) Conversion
Physical Description
Metal: White, hard, ductile, malleable solid with a bluish-gray luster.
MW: 102.9
BP: 6741°F
MLT: 3571°F
Sol: Insoluble
VP: 0 mmHg (approx)
IP: NA

Sp.Gr: 12.41 (metal)
Fl.P: NA
UEL: NA
LEL: NA

Metal: Noncombustible Solid in bulk form, but flammable as dust or powder.
Incompatibilities & Reactivities
Chlorine trifluoride, oxygen difluoride
Measurement Methods
NIOSH S188 (II-3)
Personal Protection & Sanitation
Skin: No recommendation
Eyes: No recommendation
Wash skin: No recommendation
Remove: No recommendation
Change: No recommendation

First Aid (See procedures)


Breathing: Respiratory support
Swallow: Medical attention immediately
Respirator Recommendations NIOSH/OSHA
Up to 0.5 mg/m3: (APF = 5) Any dust and mist respirator^
Up to 1 mg/m3: (APF = 10) Any dust and mist respirator except single-use and quarter-mask respirators^/(APF = 10) Any supplied-air respirator
Up to 2.5 mg/m3: (APF = 25) Any supplied-air respirator operated in a continuous-flow mode/(APF = 25) Any powered, air-purifying respirator with a dust, mist, and fume filter
Up to 5 mg/m3: (APF = 50) Any air-purifying, full-facepiece respirator with a high-efficiency particulate filter/(APF = 50) Any supplied-air respirator that has a tight-fitting facepiece and is operated in a continuous-flow mode/(APF = 50) Any powered, air-purifying respirator with a tight-fitting facepiece and a high-efficiency particulate filter/(APF = 50) Any self-contained breathing apparatus with a full facepiece/(APF = 50) Any supplied-air respirator with a full facepiece
Up to 100 mg/m3: (APF = 1000) Any supplied-air respirator operated in a pressure-demand or other positive-pressure mode
Emergency or planned entry into unknown concentrations or IDLH conditions: (APF = 10,000) Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode/(APF = 10,000) Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained positive-pressure breathing apparatus
Escape: (APF = 50) Any air-purifying, full-facepiece respirator with a high-efficiency particulate filter/Any appropriate escape-type, self-contained breathing apparatus
Exposure Routes inhalation
Symptoms Possible respiratory sensitization
Target Organs respiratory system
See also: INTRODUCTION