NIOSH Pocket Guide to Chemical Hazards

Sodium fluoride (as F) CAS 7681-49-4
NaF RTECS WB0350000
Synonyms & Trade Names
Floridine, Sodium monofluoride
DOT ID & Guide
1690 154
Exposure
Limits
NIOSH REL*: TWA 2.5 mg/m3 [*Note: The REL also applies to other inorganic, solid fluorides (as F).]
OSHA PEL*: TWA 2.5 mg/m3 [*Note: The PEL also applies to other inorganic, solid fluorides (as F).]
IDLH 250 mg/m3 (as F) Conversion
Physical Description
Odorless, white powder or colorless crystals. [Note: Pesticide grade is often dyed blue.]
MW: 42.0
BP: 3099°F
MLT: 1819°F
Sol: 4%
VP: 0 mmHg (approx)
IP: NA

Sp.Gr: 2.78
Fl.P: NA
UEL: NA
LEL: NA

Noncombustible Solid
Incompatibilities & Reactivities
Strong oxidizers
Measurement Methods
NIOSH 7902, 7906; OSHA ID110
Personal Protection & Sanitation
Skin: Prevent skin contact
Eyes: Prevent eye contact
Wash skin: When contaminated
Remove: When wet or contaminated
Change: Daily

First Aid (See procedures)
Eye: Irrigate immediately
Skin: Soap wash promptly
Breathing: Fresh air
Swallow: Medical attention immediately
Respirator Recommendations NIOSH/OSHA
Up to 12.5 mg/m3: (APF = 5) Any dust and mist respirator
Up to 25 mg/m3: (APF = 10) Any dust and mist respirator except single-use and quarter-mask respirators*/(APF = 10) Any supplied-air respirator*
Up to 62.5 mg/m3: (APF = 25) Any supplied-air respirator operated in a continuous-flow mode*/(APF = 25) Any powered, air-purifying respirator with a dust and mist filter*+
Up to 125 mg/m3: (APF = 50) Any air-purifying, full-facepiece respirator with a high-efficiency particulate filter+/(APF = 50) Any self-contained breathing apparatus with a full facepiece/(APF = 50) Any supplied-air respirator with a full facepiece
Up to 250 mg/m3: (APF = 2000) Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode
Emergency or planned entry into unknown concentrations or IDLH conditions: (APF = 10,000) Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure- demand or other positive-pressure mode/(APF = 10,000) Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained positive-pressure breathing apparatus
Escape: (APF = 50) Any air-purifying, full-facepiece respirator with a high-efficiency particulate filter+/Any appropriate escape-type, self-contained breathing apparatus
+Note: May need acid gas sorbent
Exposure Routes inhalation, ingestion, skin and/or eye contact
Symptoms Irritation eyes, respiratory system; nausea, abdominal pain, diarrhea; salivation, thirst, sweating; stiff spine; dermatitis; calcification of ligaments of ribs, pelvis
Target Organs Eyes, skin, respiratory system, central nervous system, skeleton, kidneys
See also: INTRODUCTION