NIOSH Pocket Guide to Chemical Hazards

Tetryl CAS 479-45-8
(NO2)3C6H2N(NO2)CH3 RTECS BY6300000
Synonyms & Trade Names
N-Methyl-N,2,4,6-tetranitroaniline; Nitramine; 2,4,6-Tetryl; 2,4,6-Trinitrophenyl-N-methylnitramine
DOT ID & Guide
Exposure
Limits
NIOSH REL: TWA 1.5 mg/m3 [skin]
OSHA PEL: TWA 1.5 mg/m3 [skin]
IDLH 750 mg/m3 Conversion
Physical Description
Colorless to yellow, odorless, crystalline solid.
MW: 287.2
BP: 356-374°F (Explodes)
MLT: 268°F
Sol: 0.02%
VP: <1 mmHg
IP: ?

Sp.Gr: 1.57
Fl.P: Explodes
UEL: ?
LEL: ?

Combustible Solid (Class A Explosive)
Incompatibilities & Reactivities
Oxidizable materials, hydrazine
Measurement Methods
NIOSH S225 (II-3)
Personal Protection & Sanitation
Skin: Prevent skin contact
Eyes: Prevent eye contact
Wash skin: When contaminated/Daily
Remove: When wet or contaminated
Change: Daily

First Aid (See procedures)
Eye: Irrigate immediately
Skin: Soap wash promptly
Breathing: Respiratory support
Swallow: Medical attention immediately
Respirator Recommendations NIOSH/OSHA
Up to 7.5 mg/m3: (APF = 5) Any dust and mist respirator
Up to 15 mg/m3: (APF = 10) Any dust and mist respirator except single-use and quarter-mask respirators*/(APF = 10) Any supplied-air respirator*
Up to 37.5 mg/m3: (APF = 25) Any supplied-air respirator operated in a continuous-flow mode*/(APF = 25) Any powered, air-purifying respirator with a dust and mist filter*
Up to 75 mg/m3: (APF = 50) Any air-purifying, full-facepiece respirator with a high-efficiency particulate filter/(APF = 50) Any self-contained breathing apparatus with a full facepiece/(APF = 50) Any supplied-air respirator with a full facepiece
Up to 750 mg/m3: (APF = 2000) Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode
Emergency or planned entry into unknown concentrations or IDLH conditions: (APF = 10,000) Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode/(APF = 10,000) Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained positive-pressure breathing apparatus
Escape: (APF = 50) Any air-purifying, full-facepiece respirator with a high-efficiency particulate filter/Any appropriate escape-type, self-contained breathing apparatus
Exposure Routes inhalation, skin absorption, ingestion, skin and/or eye contact
Symptoms Sensitization dermatitis, itch, erythema (skin redness); edema on nasal folds, cheeks, neck; keratitis (inflammation of the cornea); sneezing; anemia; cough, coryza; irritability; malaise (vague feeling of discomfort), headache, lassitude (weakness, exhaustion), insomnia; nausea, vomiting; liver, kidney damage
Target Organs Eyes, skin, respiratory system, central nervous system, liver, kidneys
See also: INTRODUCTION